抄録
The inapplicability of the DLVO theory to multilayered anionic bilayers is found in terms of the co-ion-valence dependence of the lamellar repeat distance. Most of the added salt is expelled from the interlamellar space to the bulk due to the Gibbs-Donnan effect on multiple bilayers with the bulk. The electrostatic double-layer interaction is well expressed by the formula recently proposed by Trefalt. The osmotic pressure due to the expelled ions, rather than the van der Waals interaction, is the main origin of the attractive force between the bilayers.
本文言語 | 英語 |
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論文番号 | 040601 |
ジャーナル | Physical Review E |
巻 | 96 |
号 | 4 |
DOI | |
出版ステータス | 出版済み - 10月 19 2017 |
!!!All Science Journal Classification (ASJC) codes
- 統計物理学および非線形物理学
- 統計学および確率
- 凝縮系物理学