Enantioselective epoxidation of olefins with chiral (salen)manganese(III) complexes bearing 4-methyl-3-[(R)-1-phenylpropyl]salicylideneamine as a constituent

Naoki Hosoya, Ryo Irie, Yoshio Ito, Tsutomu Katsuki

研究成果: Contribution to journalArticle査読

15 被引用数 (Scopus)

抄録

(Salen)manganese(III) complex 5 [2,2′-[2-methylpropane-1,2-diylbis (nitrilomethylidyne)]-5,5′ - dimethyl-6,6′ - (1-phenylpropyl)diphenolatomanganese (III)] bearing one set of stereogenic centers in the 1-phenylpropyl substituents and a geminally dimethylated ethylenediamine moiety was found to catalyze the enantioselective epoxidation of E olefins just as effectively as the reported (salen)manganese(III) complex 2, which bears two sets of stereogenic centers, in the ring substituents and on the ethylenediamine moiety.

本文言語英語
ページ(範囲)691-692
ページ数2
ジャーナルSynlett
1991
10
DOI
出版ステータス出版済み - 1 1 1991

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

フィンガープリント 「Enantioselective epoxidation of olefins with chiral (salen)manganese(III) complexes bearing 4-methyl-3-[(R)-1-phenylpropyl]salicylideneamine as a constituent」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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