Enantioselective epoxidation of olefins with chiral (Salen)manganese(III) complexes bearing 4-Methyl-3-[(R)-l-phenylpropyl] salicylideneamine as a constituent

Naoki Hosoya, Ryo Ine, Yoshio Ito, Tsutomu Katsuki

研究成果: Contribution to journalArticle査読

9 被引用数 (Scopus)

抄録

(Salen)manganese(III) complex 5 [2, 2′-[2-methylpropa-ne-li-diylbis(nitrilomethylidyne)]-5, 5′- dimethyl-6, 6′- (1-phenyl-propyl)diphenolatomanganese(III)] bearing one set of stereogenic centers in the 1-phenylpropyl substituents and a geminally dimethylated ethylenediamine moiety was found to catalyze the enantioselective epoxidation of olefins just as effectively as the reported (salen)manganese(III) complex 2, which bears two sets of stereogenic centers, in the ring substituents and on the ethylenediamine moiety.

本文言語英語
ページ(範囲)691-692
ページ数2
ジャーナルSynlett
1991
10
DOI
出版ステータス出版済み - 1 1 1991

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

フィンガープリント 「Enantioselective epoxidation of olefins with chiral (Salen)manganese(III) complexes bearing 4-Methyl-3-[(R)-l-phenylpropyl] salicylideneamine as a constituent」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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