抄録
Zoanthenol, isolated from Zoanthus sp., possesses an extremely complex architecture including contiguous quaternary carbons. An enantioselective synthesis of the fully functionalized ABC-ring of zoanthenol has been achieved and is described herein. The key features of the synthesis are the enzymatic kinetic optical resolution and the Mizoroki-Heck/Simmons-Smith reaction strategy used to construct the congested asymmetric quaternary carbons.
本文言語 | 英語 |
---|---|
ページ(範囲) | 1549-1557 |
ページ数 | 9 |
ジャーナル | Chemistry - An Asian Journal |
巻 | 3 |
号 | 8-9 |
DOI | |
出版ステータス | 出版済み - 9月 1 2008 |
外部発表 | はい |
!!!All Science Journal Classification (ASJC) codes
- 生化学
- 有機化学