Enhanced high voltage performance of LiNi0.5Mn0.3Co0.2O2cathodeviathe synergistic effect of LiPO2F2and FEC in fluorinated electrolyte for lithium-ion batteries

Rui Li, Pan Zhang, Jian Huang, Boyu Liu, Mingjiong Zhou, Bizheng Wen, Yu Luo, Shigeto Okada

研究成果: Contribution to journalArticle査読

1 被引用数 (Scopus)


LiNi0.5Mn0.3Co0.2O2can achieve high energy density due to its merits of high theoretical capacity and a relatively high operating voltage, but the LiNi0.5Mn0.3Co0.2O2battery suffers from capacity decay because of the unstable solid electrolyte interface on the cathode. Herein, we investigate the application of a fluorinated electrolyte composed of fluoroethylene carbonate (FEC) as a cosolvent and lithium difluorophosphate (LiPO2F2) as a salt-type additive extending the life span of the LiNi0.5Mn0.3Co0.2O2cathode. LiNi0.5Mn0.3Co0.2O2can achieve and maintain a capacity of 157.7 mA h g−1over 200 cycles at a 1C rate between 3.0 and 4.4 V, as well as a reversible capacity of 132.7 mA h g−1even at the high rate of 10C. The enhanced performance can be ascribed to the formation of the robust and protective fluorinated organic-inorganic film on the cathode, which derives from the FEC cosolvent and LiPO2F2additive and ensures facile lithium-ion transport. The synergistic effect of the cosolvent and additive to boost the electrochemical performance of LiNi0.5Mn0.3Co0.2O2cathode will pave a new pathway for high-voltage cathode materials.

ジャーナルRSC Advances
出版ステータス出版済み - 2 3 2021

All Science Journal Classification (ASJC) codes

  • 化学 (全般)
  • 化学工学(全般)


「Enhanced high voltage performance of LiNi<sub>0.5</sub>Mn<sub>0.3</sub>Co<sub>0.2</sub>O<sub>2</sub>cathodeviathe synergistic effect of LiPO<sub>2</sub>F<sub>2</sub>and FEC in fluorinated electrolyte for lithium-ion batteries」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。