Enhanced hydrogen desorption property of MgH2 with the addition of cerium fluorides

Huai Jun Lin, Junko Matsuda, Haiwen Li, Min Zhu, Etsuo Akiba

研究成果: Contribution to journalArticle査読

36 被引用数 (Scopus)

抄録

Abstract Hydrogen desorption property of MgH2 doped with cerium fluorides with different valences prepared using ball milling has been studied. CeF4 is catalytically active for hydrogen desorption of MgH2. Hydrogen desorption temperature and apparent activation energy of MgH2 are significantly reduced with dopant of 2 mol% of CeF4, which might be attributed to the formation of a new Ce-F-Mg specie at the CeF4/MgH2 interface and the easy electron transfer induced from the high valence Ce-cation. The apparent activation energy of hydrogen desorption of MgH2 is reduced from ∼160 kJ/mol to ∼110 kJ/mol with the dopant of CeF4.

本文言語英語
論文番号32835
ページ(範囲)S392-S396
ジャーナルJournal of Alloys and Compounds
645
S1
DOI
出版ステータス出版済み - 8 11 2015

All Science Journal Classification (ASJC) codes

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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