Enhanced photocatalytic hydrogen production on GaN–ZnO oxynitride by introduction of strain-induced nitrogen vacancy complexes

Kaveh Edalati, Ryoko Uehiro, Shuhei Takechi, Qing Wang, Makoto Arita, Motonori Watanabe, Tatsumi Ishihara, Zenji Horita

研究成果: ジャーナルへの寄稿記事

抄録

Oxynitrides are considered as new potential candidates for photocatalysis due to their lower bandgap compared with traditional oxide photocatalysts. However, the formation of native nitrogen monovacancies during the synthesis of oxynitrides reduces their photocatalytic activity due to the vacancy-induced electron/hole recombination. This study shows that a transition from the native nitrogen monovacancies to the nitrogen-based vacancy complexes in a GaN–ZnO oxynitride not only diminishes the recombination but also enhances the photocatalytic hydrogen production. Here, the vacancy complexes are introduced by mechanical straining via the high-pressure torsion (HPT) method and it is shown that the vacancy complexes reduce the bandgap and increase the over-potential for hydrogen production on the conduction band. The current results introduce a simple but effective approach to turn the nitrogen vacancies to favorable defects for photocatalysis.

元の言語英語
ページ(範囲)149-156
ページ数8
ジャーナルActa Materialia
185
DOI
出版物ステータス出版済み - 2 15 2020

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Hydrogen production
Vacancies
Nitrogen
Photocatalysis
Energy gap
Photocatalysts
Conduction bands
Torsional stress
Oxides
Defects
Electrons

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Polymers and Plastics
  • Metals and Alloys

これを引用

Enhanced photocatalytic hydrogen production on GaN–ZnO oxynitride by introduction of strain-induced nitrogen vacancy complexes. / Edalati, Kaveh; Uehiro, Ryoko; Takechi, Shuhei; Wang, Qing; Arita, Makoto; Watanabe, Motonori; Ishihara, Tatsumi; Horita, Zenji.

:: Acta Materialia, 巻 185, 15.02.2020, p. 149-156.

研究成果: ジャーナルへの寄稿記事

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AU - Edalati, Kaveh

AU - Uehiro, Ryoko

AU - Takechi, Shuhei

AU - Wang, Qing

AU - Arita, Makoto

AU - Watanabe, Motonori

AU - Ishihara, Tatsumi

AU - Horita, Zenji

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