Enhancement of reaction efficiency by functionalized alcohols on gold(I)-catalyzed intermodular hydroalkoxylation of unactivated olefins

Toshifumi Hirai, Aklyuki Hamasaki, Aki Nakamura, Makoto Tokunaga

研究成果: ジャーナルへの寄稿記事

44 引用 (Scopus)

抄録

"Chemical Equation Presented" Intermolecular hydroalkoxylation of unactivated olefins catalyzed by the combination of gold(I) and electron deficient phosphine ligands has been developed. Although pairings of unactivated olefins and common aliphatic alcohols gave unsatisfactory results In gold catalyzed hydroalkoxylations, the use of alcohol substrates bearing coordination functionalities such as halogen or alkoxy groups showed great improvement of reactivity.

元の言語英語
ページ(範囲)5510-5513
ページ数4
ジャーナルOrganic Letters
11
発行部数23
DOI
出版物ステータス出版済み - 12 3 2009

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phosphine
Alkenes
Gold
alkenes
alcohols
Bearings (structural)
Alcohols
gold
Halogens
augmentation
phosphines
halogens
reactivity
Electrons
Ligands
ligands
Substrates
electrons
alkoxyl radical

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

これを引用

Enhancement of reaction efficiency by functionalized alcohols on gold(I)-catalyzed intermodular hydroalkoxylation of unactivated olefins. / Hirai, Toshifumi; Hamasaki, Aklyuki; Nakamura, Aki; Tokunaga, Makoto.

:: Organic Letters, 巻 11, 番号 23, 03.12.2009, p. 5510-5513.

研究成果: ジャーナルへの寄稿記事

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