ESR of the Cationic Triradical of 1,3,5-Tris(diphenylamino)benzene

Kazunari Yoshizawa, Akihisa Chano, Akihiro Ito, Kazuyoshi Tanaka, Tokio Yamabe, Hideo Fujita, Jim Yamauchi, Motoo Shiro

研究成果: Contribution to journalArticle

119 被引用数 (Scopus)

抄録

The ESR spectrum of the cationic triradical of 1,3,5-tris(diphenylamino)benzene (TDAB) is discussed. The tricationic state of TDAB was observed by means of cyclic voltammetry. The orange cationic triradical was prepared by oxidation of TDAB with trifluoroacetic anhydride in the presence of tetra-n-butylammonium tetrafluoroborate in CH2Cl2. The ESR spectrum of the randomly oriented radicals in the CH2Cl2 glass agrees well with the theoretical prediction of a quartet (S = 3/2) spin state with a zero-field splitting parameter D′ of 13.1 G (0.0012 cm-1). This is the first observation of a high-spin state of a cationic radical.

本文言語英語
ページ(範囲)5994-5998
ページ数5
ジャーナルJournal of the American Chemical Society
114
15
DOI
出版ステータス出版済み - 7 1 1992
外部発表はい

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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