TY - JOUR
T1 - Expanding frontiers in materials chemistry and physics with multiple anions
AU - Kageyama, Hiroshi
AU - Hayashi, Katsuro
AU - Maeda, Kazuhiko
AU - Attfield, J. Paul
AU - Hiroi, Zenji
AU - Rondinelli, James M.
AU - Poeppelmeier, Kenneth R.
N1 - Funding Information:
We thank Dr. Fumitaka Takeiri, Prof. Kyoko Ishizaka, Dr. Kohei Miyazaki, Prof. Shuichi Murakami, Dr. Yoji Kobayashi, Dr. Hiraku Ogino, and Prof. Yutaka Ueda for helpful discussions. Financial support from the JSPS Grant-in-Aid for Scientific Research on Innovative Areas “Mixed anion” (16H06439, 16H06440, 16H06441, and 16K21724) and CREST (JPMJCR1421) from JST is acknowledged. K.R.P. and J.M.R. were supported by the National Science Foundation’s MRSEC program (DMR-1720139) at the Materials Research Center of Northwestern University.
Publisher Copyright:
© 2018 The Author(s).
PY - 2018/12/1
Y1 - 2018/12/1
N2 - During the last century, inorganic oxide compounds laid foundations for materials synthesis, characterization, and technology translation by adding new functions into devices previously dominated by main-group element semiconductor compounds. Today, compounds with multiple anions beyond the single-oxide ion, such as oxyhalides and oxyhydrides, offer a new materials platform from which superior functionality may arise. Here we review the recent progress, status, and future prospects and challenges facing the development and deployment of mixed-anion compounds, focusing mainly on oxide-derived materials. We devote attention to the crucial roles that multiple anions play during synthesis, characterization, and in the physical properties of these materials. We discuss the opportunities enabled by recent advances in synthetic approaches for design of both local and overall structure, state-of-the-art characterization techniques to distinguish unique structural and chemical states, and chemical/physical properties emerging from the synergy of multiple anions for catalysis, energy conversion, and electronic materials.
AB - During the last century, inorganic oxide compounds laid foundations for materials synthesis, characterization, and technology translation by adding new functions into devices previously dominated by main-group element semiconductor compounds. Today, compounds with multiple anions beyond the single-oxide ion, such as oxyhalides and oxyhydrides, offer a new materials platform from which superior functionality may arise. Here we review the recent progress, status, and future prospects and challenges facing the development and deployment of mixed-anion compounds, focusing mainly on oxide-derived materials. We devote attention to the crucial roles that multiple anions play during synthesis, characterization, and in the physical properties of these materials. We discuss the opportunities enabled by recent advances in synthetic approaches for design of both local and overall structure, state-of-the-art characterization techniques to distinguish unique structural and chemical states, and chemical/physical properties emerging from the synergy of multiple anions for catalysis, energy conversion, and electronic materials.
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U2 - 10.1038/s41467-018-02838-4
DO - 10.1038/s41467-018-02838-4
M3 - Review article
C2 - 29472526
AN - SCOPUS:85042546044
VL - 9
JO - Nature Communications
JF - Nature Communications
SN - 2041-1723
IS - 1
M1 - 772
ER -