Experimental and theoretical evidence for nonheme iron(III) alkylperoxo species as sluggish oxidants in oxygenation reactions

Mi Sook Seo, Takashi Kamachi, Tomohisa Kouno, Koji Murata, Mi Joo Park, Kazunari Yoshizawa, Wonwoo Nam

研究成果: Contribution to journalArticle査読

52 被引用数 (Scopus)

抄録

The active oxidant that oxygenates organic substrates is an iron(IV) oxo intermediate, namely, [(tpa)FeIV(O)(CH3CN)]2+ (2), which is formed through O-O bond homolysis, according to experimental and computational studies on the reactivity of nonheme iron(III) alkylperoxo complex [(tpa)FeIII(OOtBu)(CH3CN)]2+ (1), which was shown to be a sluggish electrophilic oxidant that is incapable of oxygenating organic substrates. tpa = tris(2-pyridylmethyl)amine. (Chemical Equation Presented).

本文言語英語
ページ(範囲)2291-2294
ページ数4
ジャーナルAngewandte Chemie - International Edition
46
13
DOI
出版ステータス出版済み - 6 29 2007

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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