Experimental study of reductive elimination of H 2 from rhodium hydride species

Daisuke Inoki; Takahiro Matsumoto; Hidetaka Nakai; Seiji Ogo

doi:10.1021/om2009759

Experimental study of reductive elimination of H ₂ from rhodium hydride species

Daisuke Inoki, Takahiro Matsumoto, Hidetaka Nakai, Seiji Ogo

研究成果: Contribution to journal › Article › 査読

20 被引用数 (Scopus)

抄録

A Rh ^III monohydride terpyridine complex undergoes reductive elimination of H ₂ in CH ₃CN to form a dinuclear Rh ^II complex with a metal-metal bond. Kinetic studies have revealed that the conversion from the monohydride species to the dinuclear species with evolution of H ₂ obeys first-order kinetics and have determined the kinetic deuterium isotope effect value to be 2.0. We discuss the mechanism for the reductive elimination of H ₂ from rhodium hydride species.

本文言語	英語
ページ（範囲）	2996-3001
ページ数	6
ジャーナル	Organometallics
巻	31
号	8
DOI	https://doi.org/10.1021/om2009759
出版ステータス	出版済み - 4 23 2012

All Science Journal Classification (ASJC) codes

物理化学および理論化学
有機化学
無機化学

文献へのアクセス

10.1021/om2009759

他のファイルとリンク

引用スタイル

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abstract = "A Rh III monohydride terpyridine complex undergoes reductive elimination of H 2 in CH 3CN to form a dinuclear Rh II complex with a metal-metal bond. Kinetic studies have revealed that the conversion from the monohydride species to the dinuclear species with evolution of H 2 obeys first-order kinetics and have determined the kinetic deuterium isotope effect value to be 2.0. We discuss the mechanism for the reductive elimination of H 2 from rhodium hydride species.",

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