Extraction of lanthanide ions with an organophosphorous extractant into ionic liquids

Fukiko Kubota, Yusuke Koyanagi, Kazunori Nakashima, Kojiro Shimojo, Noriho Kamiya, Masahiro Goto

研究成果: Contribution to journalArticle査読

24 被引用数 (Scopus)

抄録

Extraction of lanthanide ions was carried out with the organophosphorous extractant PC-88A dissolved in an imidazolium-based ionic liquid. PC-88A was soluble in ionic liquids having long-chain alkyl substituents such as octyl and dodecyl groups, [C8mim] and [C12mim][TFSI], although short-chain imidazolium ionic liquids could not solubilize the extractant. The extraction equilibrium observed in the ionic liquid system was similar to that in the n-dodecane system, and the extraction behavior could be explained by the same proton exchange mechanism as for the conventional organic solvent system, although the extraction efficiency was not improved. An ionic liquid having shorter alkyl chain [C8mim] showed a higher extraction ability than [C12mim][TFSI]. Stripping of the metal ions from the ionic liquids was also examined. Quantitative stripping of the metal ions was achieved by nitric acid in the [C12mim][TFSI] system.

本文言語英語
ページ(範囲)81-87
ページ数7
ジャーナルSolvent Extraction Research and Development
15
出版ステータス出版済み - 9 9 2008

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

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