Facile preparation of monolithic LiFePO4/carbon composites with well-defined macropores for a lithium-ion battery

George Hasegawa, Yuya Ishihara, Kazuyoshi Kanamori, Kohei Miyazaki, Yuki Yamada, Kazuki Nakanishi, Takeshi Abe

研究成果: Contribution to journalArticle査読

72 被引用数 (Scopus)

抄録

A novel and facile method for the preparation of monolithic LiFePO 4/carbon composites with well-defined macropores has been developed. The precursor macroporous gels consisting of inorganic networks as well as organic polymers were fabricated by the epoxide-mediated sol-gel method accompanied by phase separation. The inorganic-organic hybrid gels were calcined under an inert atmosphere, resulting in LiFePO4/carbon monoliths. The influence of the starting compositions on the gel morphologies has been investigated, and the constituents of the gel network were discussed. The reaction mechanism of the crystallization of LiFePO4 from green bodies during calcination has also been investigated by thermal analysis, X-ray diffraction, and Raman scattering. In addition, the electrochemical properties of the resultant LiFePO4/carbon composites were examined by the charge-discharge test.

本文言語英語
ページ(範囲)5208-5216
ページ数9
ジャーナルChemistry of Materials
23
23
DOI
出版ステータス出版済み - 12 13 2011

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

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