Ferroelectric and luminescence properties of zinc(ii) and platinum(ii) soft complexes

Ryohei Akiyoshi, Yuma Hirota, Daisuke Kosumi, Ryo Ohtani, Masaaki Nakamura, Leonard F. Lindoy, Shinya Hayami

研究成果: ジャーナルへの寄稿記事

1 引用 (Scopus)

抄録

Zinc(ii) and platinum(ii) complexes [M(X-4-C18-salmmen)] (M = Zn (1) and Pt (2), X = R, S (optical isomer) and rac (racemate), salmmen = N,N′-monomethylenebis-salicylideneimine) were synthesized and investigated. The series of compounds represented by 1 (R, S and rac forms) display liquid crystalline state behaviour at 413 K, and exhibit both ferroelectric and fluorescence properties, while the compounds represented by 2 (R and S, and rac forms) do not display liquid crystal behaviour but do exhibit ferroelectric and fluorescence properties. The ferroelectric behaviour was confirmed by second harmonic generation (SHG) experiments. It is considered that the motion and fluctuation of the long alkyl chains in these complexes results in the observed ferroelectric properties.

元の言語英語
ページ(範囲)14288-14292
ページ数5
ジャーナルDalton Transactions
47
発行部数40
DOI
出版物ステータス出版済み - 1 1 2018

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Platinum
Ferroelectric materials
Luminescence
Zinc
Fluorescence
Harmonic generation
Liquid crystal displays
Isomers
Crystalline materials
Liquids
Experiments

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

これを引用

Akiyoshi, R., Hirota, Y., Kosumi, D., Ohtani, R., Nakamura, M., Lindoy, L. F., & Hayami, S. (2018). Ferroelectric and luminescence properties of zinc(ii) and platinum(ii) soft complexes. Dalton Transactions, 47(40), 14288-14292. https://doi.org/10.1039/c8dt01100a

Ferroelectric and luminescence properties of zinc(ii) and platinum(ii) soft complexes. / Akiyoshi, Ryohei; Hirota, Yuma; Kosumi, Daisuke; Ohtani, Ryo; Nakamura, Masaaki; Lindoy, Leonard F.; Hayami, Shinya.

:: Dalton Transactions, 巻 47, 番号 40, 01.01.2018, p. 14288-14292.

研究成果: ジャーナルへの寄稿記事

Akiyoshi, R, Hirota, Y, Kosumi, D, Ohtani, R, Nakamura, M, Lindoy, LF & Hayami, S 2018, 'Ferroelectric and luminescence properties of zinc(ii) and platinum(ii) soft complexes', Dalton Transactions, 巻. 47, 番号 40, pp. 14288-14292. https://doi.org/10.1039/c8dt01100a
Akiyoshi, Ryohei ; Hirota, Yuma ; Kosumi, Daisuke ; Ohtani, Ryo ; Nakamura, Masaaki ; Lindoy, Leonard F. ; Hayami, Shinya. / Ferroelectric and luminescence properties of zinc(ii) and platinum(ii) soft complexes. :: Dalton Transactions. 2018 ; 巻 47, 番号 40. pp. 14288-14292.
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