Flow injection determination of anionic polyelectrolytes using an anionic surfactant-selective plasticized poly(vinyl chloride) membrane electrode detector

Takashi Masadome, Toshihiko Imato, Satoshi Itoh, Yasukazu Asano

    研究成果: Contribution to journalArticle査読

    10 被引用数 (Scopus)

    抄録

    A potentiometric flow injection method for the determination of anionic polyelectrolytes utilizing a flow-through type surfactant-selective electrode detector is described. The method is based on the detection of the concentration increase of anionic surfactant liberated from a reagent stream containing an ion associate between cationic polyelectrolyte, poly(diallyldimethylammonium chloride) and anionic surfactant, dodecylbenzenesulfonate, which is caused by the formation of a polyion complex between cationic and anionic polyelectrolytes. The response of the electrode detector as a peak-shaped signal was obtained for injected anionic polyelectrolyte samples. A linear relationship was found to exist between peak height and the logarithmic concentration of potassium poly (vinyl sulfate) (PVSK) with a slope of 30 mV decade-1 in a concentration range of 1.0 × 10-4 to 1.0 × 10-3 mol/L. Identical relationships were obtained for sodium alginate and carageenan (also anionic polyelectrolytes) as for PVSK but with a lower sensitivity. The detection limit for PVSK was 2.5 × 10-5 mol/L. The relative standard deviation for 5 injections of a 2.5 × 10-4 mol/L PVSK solution was 1.3% and the sampling rate was ca. 10 samples h-1.

    本文言語英語
    ページ(範囲)901-903
    ページ数3
    ジャーナルFresenius' Journal of Analytical Chemistry
    357
    7
    DOI
    出版ステータス出版済み - 1997

    All Science Journal Classification (ASJC) codes

    • Biochemistry

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