Fluorescent lifetime measurement for dye molecules tagged to polystyrene in a thin film; analysis for thermal molecular motion of a polymer thin film

Yu Tsuchimura, Keiji Tanaka, Toshihiko Nagamura

研究成果: 会議への寄与タイプ論文

抄録

Fluorescence lifetime for 6-(N-(7-nitrobenz-2-oxa-1,3-diazol-4-yl)amino) hexanoic acid (NBD) tagged to polystyrene (PS) in a film on a sapphire substrate was examined as a function of temperature. Mode-locked Ti:Sapphire picosecond laser at 430 nm was irradiated from the substrate side. The substrate interface was selectively excited by evanescent wave excitation, lifetime decreased with increasing temperature because the fractional amount of non-radiative pathways to the ground state for excited NBD molecules increased with temperature. In general, as measuring temperature goes beyond a temperature at which molecular motion releases, the slope for the temperature-lifetime changes. In this experiment, the inflection point was higher in the interfacial region than in the internal bulk phase of the film. Thus, it was concluded that chain mobility in the interfacial region is restricted in comparison with that in the bulk phase.

元の言語英語
ページ数1
出版物ステータス出版済み - 12 1 2005
イベント54th SPSJ Annual Meeting 2005 - Yokohama, 日本
継続期間: 5 25 20055 27 2005

その他

その他54th SPSJ Annual Meeting 2005
日本
Yokohama
期間5/25/055/27/05

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Polymer films
Polystyrenes
Dyes
Thin films
Molecules
Sapphire
Temperature
Substrates
Laser modes
Ground state
Hot Temperature
Amino acids
Fluorescence
Lasers
Experiments

All Science Journal Classification (ASJC) codes

  • Engineering(all)

これを引用

Tsuchimura, Y., Tanaka, K., & Nagamura, T. (2005). Fluorescent lifetime measurement for dye molecules tagged to polystyrene in a thin film; analysis for thermal molecular motion of a polymer thin film. 論文発表場所 54th SPSJ Annual Meeting 2005, Yokohama, 日本.

Fluorescent lifetime measurement for dye molecules tagged to polystyrene in a thin film; analysis for thermal molecular motion of a polymer thin film. / Tsuchimura, Yu; Tanaka, Keiji; Nagamura, Toshihiko.

2005. 論文発表場所 54th SPSJ Annual Meeting 2005, Yokohama, 日本.

研究成果: 会議への寄与タイプ論文

Tsuchimura, Y, Tanaka, K & Nagamura, T 2005, 'Fluorescent lifetime measurement for dye molecules tagged to polystyrene in a thin film; analysis for thermal molecular motion of a polymer thin film', 論文発表場所 54th SPSJ Annual Meeting 2005, Yokohama, 日本, 5/25/05 - 5/27/05.
Tsuchimura, Yu ; Tanaka, Keiji ; Nagamura, Toshihiko. / Fluorescent lifetime measurement for dye molecules tagged to polystyrene in a thin film; analysis for thermal molecular motion of a polymer thin film. 論文発表場所 54th SPSJ Annual Meeting 2005, Yokohama, 日本.1 p.
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