Fluoropolymer Surfaces/Interfaces

Yuji Higaki, Ryohei Ishige, Atsushi Takahara

研究成果: 書籍/レポート タイプへの寄稿

3 被引用数 (Scopus)

抄録

Polymers with perfluoroalkyl (Rf) groups have surface characteristics that differ greatly from those of comparable hydrogenated structures, for example, excellent chemical and thermal stability, nonadhesive properties, low friction coefficients, low surface free energies, and antifouling behavior. Fluoropolymers with Rf groups have been extensively studied in various research fields and applied as very meaningful and valuable chemicals in industry. This chapter introduces the recent investigation relating to the surface molecular aggregation structure and surface molecular motion of the fluoro(co)polymers with Rf side group. Grazing-incidence wide-angle X-ray diffraction (GI-WAXD) measurement and X-ray photoelectron spectroscopy (XPS) using C60 ion beam were applied to the surface molecular aggregation structure analysis and the depth analysis of the fluoropolymer films, respectively. In situ neutron reflectivity (NR) measurement affords detail insights of the swelling state of semicrystalline CO2-philic fluoropolymer brushes in supercritical carbon dioxide.

本文言語英語
ホスト出版物のタイトルHandbook of Fluoropolymer Science and Technology
出版社Wiley-Blackwell
ページ433-450
ページ数18
ISBN(電子版)9781118850220
ISBN(印刷版)9780470079935
DOI
出版ステータス出版済み - 5月 27 2014

!!!All Science Journal Classification (ASJC) codes

  • 材料科学(全般)

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