Formation and spectroscopic characterization of the carbon monoxide adduct of an alkanethiolate-coordinated heme

Mikiya Matsu-Ura, Fumito Tani, Yoshinori Naruta

研究成果: Contribution to journalArticle査読

3 被引用数 (Scopus)

抄録

The CO adduct of a thiolate-coordinated heme was obtained by two different methods and characterized by UV-vis and resonance Raman spectroscopy. The v(Fe-CO) band was observed at 428 cm-1. The unusually low frequency indicates the extremely strong σ-donation from the thiolate axial ligand to the heme iron.

本文言語英語
ページ(範囲)814-815
ページ数2
ジャーナルChemistry Letters
7
DOI
出版ステータス出版済み - 1 1 2000

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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