Formation of gold clusters on La-Ni mixed oxides and its catalytic performance for isomerization of allylic alcohols to saturated aldehydes

Tamao Ishida, Jun Aimoto, Akiyuki Hamasaki, Hironori Ohashi, Tetsuo Honma, Takushi Yokoyama, Kohei Sakata, Mitsutaka Okumura, Makoto Tokunaga

研究成果: Contribution to journalArticle査読

5 被引用数 (Scopus)

抄録

Au/NiO catalyzed the isomerization of allylic alcohols to afford saturated aldehydes. LaNi mixed oxide could stabilize Au(III) and afford gold clusters smaller than 1 nm by H2reduction. The resulting Au clusters on La-Ni-O exhibited superior catalytic performance to Au/NiO for the isomerization of internal allylic alcohol, 2-octen-1-ol to octanal.

本文言語英語
ページ(範囲)1368-1370
ページ数3
ジャーナルChemistry Letters
43
8
DOI
出版ステータス出版済み - 2014

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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