Formation of silicato complexes of aluminium in aqueous solution

Takushi Yokoyama; Chiho Yamanaka; Toshikazu Tarutani

doi:10.1016/S0021-9673(00)96349-0

Formation of silicato complexes of aluminium in aqueous solution

Takushi Yokoyama, Chiho Yamanaka, Toshikazu Tarutani

無機・分析化学

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

17 被引用数 (Scopus)

抄録

The formation of silicate complexes of aluminium in aqueous solution at pH 8 was studied by chromatography and flow injection analysis. Most of the aluminium formed anionic species with AlOSi bonds in monosilicic acid solution. A complex A₂L₆ (A = aluminium; L = Si in silicic acid) could be separated on a Sephadex G-50 column. The existence of mononuclear complexes of aluminium, AL₃ and AL₄, was suggested from an adsorption experiment on an anion-exchange resin.

本文言語	英語
ページ（範囲）	151-157
ページ数	7
ジャーナル	Journal of Chromatography A
巻	403
号	C
DOI	https://doi.org/10.1016/S0021-9673(00)96349-0
出版ステータス	出版済み - 1987

!!!All Science Journal Classification (ASJC) codes

分析化学
生化学
有機化学

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10.1016/S0021-9673(00)96349-0

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title = "Formation of silicato complexes of aluminium in aqueous solution",

abstract = "The formation of silicate complexes of aluminium in aqueous solution at pH 8 was studied by chromatography and flow injection analysis. Most of the aluminium formed anionic species with AlOSi bonds in monosilicic acid solution. A complex A2L6 (A = aluminium; L = Si in silicic acid) could be separated on a Sephadex G-50 column. The existence of mononuclear complexes of aluminium, AL3 and AL4, was suggested from an adsorption experiment on an anion-exchange resin.",

author = "Takushi Yokoyama and Chiho Yamanaka and Toshikazu Tarutani",

year = "1987",

doi = "10.1016/S0021-9673(00)96349-0",

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journal = "Journal of Chromatography A",

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T1 - Formation of silicato complexes of aluminium in aqueous solution

AU - Yokoyama, Takushi

AU - Yamanaka, Chiho

AU - Tarutani, Toshikazu

PY - 1987

Y1 - 1987

N2 - The formation of silicate complexes of aluminium in aqueous solution at pH 8 was studied by chromatography and flow injection analysis. Most of the aluminium formed anionic species with AlOSi bonds in monosilicic acid solution. A complex A2L6 (A = aluminium; L = Si in silicic acid) could be separated on a Sephadex G-50 column. The existence of mononuclear complexes of aluminium, AL3 and AL4, was suggested from an adsorption experiment on an anion-exchange resin.

AB - The formation of silicate complexes of aluminium in aqueous solution at pH 8 was studied by chromatography and flow injection analysis. Most of the aluminium formed anionic species with AlOSi bonds in monosilicic acid solution. A complex A2L6 (A = aluminium; L = Si in silicic acid) could be separated on a Sephadex G-50 column. The existence of mononuclear complexes of aluminium, AL3 and AL4, was suggested from an adsorption experiment on an anion-exchange resin.

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U2 - 10.1016/S0021-9673(00)96349-0

DO - 10.1016/S0021-9673(00)96349-0

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AN - SCOPUS:0003411011

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JO - Journal of Chromatography A

JF - Journal of Chromatography A

SN - 0021-9673

IS - C

ER -

Formation of silicato complexes of aluminium in aqueous solution

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!!!All Science Journal Classification (ASJC) codes

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