Formation of the ζ phase at an interface between an Fe substrate and a molten 0.2 mass% Al-Zn during galvannealing

T. Kato, K. Nunome, K. Kaneko, H. Saka

研究成果: ジャーナルへの寄稿学術誌査読

92 被引用数 (Scopus)

抄録

An interstitial free (IF) steel was dipped in a bath of molten Zn containing 0.2 mass% Al. The asdipped (galvanized) steel was then annealed above the melting point of Zn (galvannealed), say at 773 K, for a period ranging from 1 to 30 s. Evolution of the microstructure of the Zn-containing coating was examined by transmission electron microscopy (TEM) and the chemical composition around the Zn(Al)/Fe interface was analyzed by energy dispersion spectroscopy (EDS) in a dedicated scanning transmission electron microscope (STEM). In the as-dipped (galvanized) steel a continuous layer of Fe2Al5 existed at the Zn(Al)/Fe interface, but no Fe-Zn intermetallic compounds were observed. Galvannealing at 773 K for 1 s resulted in the formation of the ζ phase at the Zn(Al)/Fe2Al5 interface, which grew at the expense of the Zn(Al) coating during the subsequent galvannealing. Possible mechanisms of nucleation of Fe-Zn intermetallic compounds are discussed.

本文言語英語
ページ(範囲)2257-2262
ページ数6
ジャーナルActa Materialia
48
9
DOI
出版ステータス出版済み - 5月 29 2000
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 電子材料、光学材料、および磁性材料
  • セラミックおよび複合材料
  • ポリマーおよびプラスチック
  • 金属および合金

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