Friedel-Crafts functionalization of the cyclopentadienyl ligand in buckymetallocenes

Yutaka Matsuo, Yoichiro Kuninobu, Shingo Ito, Masaya Sawamura, Eiichi Nakamura

研究成果: ジャーナルへの寄稿記事

4 引用 (Scopus)

抄録

Acylated buckyferrocene and ruthenocene, Fe(η5-C 60Me5)(η5-C5H4COR) (R = Me, Ph, and CHCHPh) and Ru(η5-C60Me 5)(η5-C5H4COR) (R = Me and Ph), were obtained by Friedel-Crafts acylation of the parent buckymetallocenes with the corresponding acid chlorides and aluminum chloride in carbon disulfide at ambient temperature. The electron withdrawing and sterically hindered nature of the acyl groups were revealed by X-ray crystallography, infrared spectroscopy and electrochemical measurements. The possibility of further derivatizing the acylated products was illustrated by the conversion of the acetyl buckyruthenocene into the corresponding hydroxy and acetoxy compounds Ru(η5-C60Me5)(η5-C 5H4CH(OH)Me) and Ru(η5-C 60Me5)(η5-C5H 4CH(OAc)Me). This journal is

元の言語英語
ページ(範囲)7407-7412
ページ数6
ジャーナルDalton Transactions
43
発行部数20
DOI
出版物ステータス出版済み - 5 28 2014

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Carbon Disulfide
Acylation
X ray crystallography
Infrared spectroscopy
Ligands
Acids
Electrons
Temperature
ruthenocene
aluminum chloride

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

これを引用

Friedel-Crafts functionalization of the cyclopentadienyl ligand in buckymetallocenes. / Matsuo, Yutaka; Kuninobu, Yoichiro; Ito, Shingo; Sawamura, Masaya; Nakamura, Eiichi.

:: Dalton Transactions, 巻 43, 番号 20, 28.05.2014, p. 7407-7412.

研究成果: ジャーナルへの寄稿記事

Matsuo, Yutaka ; Kuninobu, Yoichiro ; Ito, Shingo ; Sawamura, Masaya ; Nakamura, Eiichi. / Friedel-Crafts functionalization of the cyclopentadienyl ligand in buckymetallocenes. :: Dalton Transactions. 2014 ; 巻 43, 番号 20. pp. 7407-7412.
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AU - Nakamura, Eiichi

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