Frontispiece

Heterometallic FeIII/K Coordination Polymer with a Wide Thermal Hysteretic Spin Transition at Room Temperature

研究成果: ジャーナルへの寄稿記事

1 引用 (Scopus)

抄録

The FeIII anionic complex exhibiting cooperative spin transition with a wide thermal hysteresis near room temperature, K[Fe(5-Brthsa)2] (5-Brthsa-H2=5-bromosalicylaldehyde thiosemicarbazone), is reported. The hysteresis shows a one-step transition in heating mode and a two-step transition in cooling mode. X-ray structure analysis shows the coexistence of hydrogen bond and cation-π interactions, along with metal coordination bonds, to give 2D coordination polymer structure.

元の言語英語
ページ数1
ジャーナルChemistry - A European Journal
22
発行部数2
DOI
出版物ステータス出版済み - 1 1 2016

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Hysteresis
Polymers
Thiosemicarbazones
Cations
Hydrogen bonds
Positive ions
Metals
Cooling
Heating
X rays
Temperature
Hot Temperature
5-bromosalicylaldehyde

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

これを引用

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abstract = "The FeIII anionic complex exhibiting cooperative spin transition with a wide thermal hysteresis near room temperature, K[Fe(5-Brthsa)2] (5-Brthsa-H2=5-bromosalicylaldehyde thiosemicarbazone), is reported. The hysteresis shows a one-step transition in heating mode and a two-step transition in cooling mode. X-ray structure analysis shows the coexistence of hydrogen bond and cation-π interactions, along with metal coordination bonds, to give 2D coordination polymer structure.",
author = "Soonchul Kang and Yoshihito Shiota and Akira Kariyazaki and Shinji Kanegawa and Kazunari Yoshizawa and Osamu Sato",
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AU - Kang, Soonchul

AU - Shiota, Yoshihito

AU - Kariyazaki, Akira

AU - Kanegawa, Shinji

AU - Yoshizawa, Kazunari

AU - Sato, Osamu

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N2 - The FeIII anionic complex exhibiting cooperative spin transition with a wide thermal hysteresis near room temperature, K[Fe(5-Brthsa)2] (5-Brthsa-H2=5-bromosalicylaldehyde thiosemicarbazone), is reported. The hysteresis shows a one-step transition in heating mode and a two-step transition in cooling mode. X-ray structure analysis shows the coexistence of hydrogen bond and cation-π interactions, along with metal coordination bonds, to give 2D coordination polymer structure.

AB - The FeIII anionic complex exhibiting cooperative spin transition with a wide thermal hysteresis near room temperature, K[Fe(5-Brthsa)2] (5-Brthsa-H2=5-bromosalicylaldehyde thiosemicarbazone), is reported. The hysteresis shows a one-step transition in heating mode and a two-step transition in cooling mode. X-ray structure analysis shows the coexistence of hydrogen bond and cation-π interactions, along with metal coordination bonds, to give 2D coordination polymer structure.

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