Fuel cell electrocatalyst using polybenzimidazole-modified carbon nanotubes as support materials

Tsuyohiko Fujigaya, Naotoshi Nakashima

    研究成果: ジャーナルへの寄稿学術誌査読

    148 被引用数 (Scopus)

    抄録

    Toward the next generation fuel cell systems, the development of a novel electrocatalyst for the polymer electrolyte fuel cell (PEFC) is crucial to overcome the drawbacks of the present electrocatalyst. As a conductive supporting material for the catalyst, carbon nanotubes (CNTs) have emerged as a promising candidate, and many attempts have been carried out to introduce CNT, in place of carbon black. On the other hand, as a polymer electrolyte, polybenzimidazoles (PBIs) have been recognized as a powerful candidate due to the high proton conductivity above 100 °C under non-humid conditions. In 2008, we found that these two materials have a strong physical interaction and form a stable hybrid material, in which the PBIs uniformly wrap the surfaces of the CNTs. Furthermore, PBIs serve as effective binding sites for the formation of platinum (Pt) nanoparticles to fabricate a ternary composite (CNT/PBIs/Pt). In this review article, we summarize the fundamental properties of the CNT/PBIs/Pt and discuss their potential as a new electrocatalyst for the PEFC in comparison with the conventional ones. Furthermore, potential applications of CNT/PBIs including use of the materials for oxygen reduction catalysts and reinforcement of PBI films are summarized.

    本文言語英語
    ページ(範囲)1666-1681
    ページ数16
    ジャーナルAdvanced Materials
    25
    12
    DOI
    出版ステータス出版済み - 3月 25 2013

    !!!All Science Journal Classification (ASJC) codes

    • 材料科学(全般)
    • 材料力学
    • 機械工学

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