Geometric pumping induced by shear flow in dilute liquid crystalline polymer solutions

Shunsuke Yabunaka, Hisao Hayakawa

研究成果: ジャーナルへの寄稿学術誌査読

抄録

We investigate nonlinear rheology of dilute liquid crystalline polymer solutions under time dependent two-directional shear flow. We analyze the Smoluchowski equation, which describes the dynamics of the orientation of a liquid crystalline polymer, by employing technique of the full counting statistics. In the adiabatic limit, we derive the expression for time integrated currents generated by a Berry-like curvature. Using this expression, it is shown that the expectation values of the time-integrated angular velocity of a liquid crystalline polymer and the time-integrated stress tensor are generally not zero even if the time average of the shear rate is zero. The validity of the theoretical calculations is confirmed by direct numerical simulations of the Smoluchowski equation. Nonadiabatic effects are also investigated by means of simulations and it is found that the time-integrated stress tensor depends on the speed of the modulation of the shear rate if we adopt the isotropic distribution as an initial state.

本文言語英語
論文番号054903
ジャーナルJournal of Chemical Physics
142
5
DOI
出版ステータス出版済み - 2月 7 2015
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 物理学および天文学(全般)
  • 物理化学および理論化学

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