Glycopolymer preparation via post-polymerization modification using N-succinimidyl monomers

Tomohiro Fukuda, Sotaro Tsuji, Yoshiko Miura

研究成果: ジャーナルへの寄稿記事

抄録

N-succinimidyl monomers such as N-methacryloxysuccinimide (MASI) and N-acryloxysuccinimide (ASI) were utilized as prepolymers to synthesize glycopolymers via postpolymerization modification. Living radical polymerization with RAFT agents succeeded using not only MASI but also ASI. While the polymerization with ATRP initiator did not succeed using ASI, the procedure was successful with MASI. MASI was also applicable for SI-ATRP reactions on substrate surfaces. The introduction rate of NH 2 -terminated saccharide onto the prepolymer via amine coupling reaction was affected by the reaction temperature. This preparation procedure via postpolymerization modification is expected to provide a facile method for various functional polymers, such as other saccharide and beneficial ligands. [Figure not available: see fulltext.].

元の言語英語
ページ(範囲)617-625
ページ数9
ジャーナルPolymer Journal
51
発行部数6
DOI
出版物ステータス出版済み - 6 1 2019

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Atom transfer radical polymerization
Monomers
Polymerization
Functional polymers
Living polymerization
Free radical polymerization
Amines
Ligands
Substrates
Temperature

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics
  • Materials Chemistry

これを引用

Glycopolymer preparation via post-polymerization modification using N-succinimidyl monomers. / Fukuda, Tomohiro; Tsuji, Sotaro; Miura, Yoshiko.

:: Polymer Journal, 巻 51, 番号 6, 01.06.2019, p. 617-625.

研究成果: ジャーナルへの寄稿記事

Fukuda, Tomohiro ; Tsuji, Sotaro ; Miura, Yoshiko. / Glycopolymer preparation via post-polymerization modification using N-succinimidyl monomers. :: Polymer Journal. 2019 ; 巻 51, 番号 6. pp. 617-625.
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