Gram-scale synthesis of nickel(II) norcorrole

The smallest antiaromatic porphyrinoid

Tomohiro Ito, Yosuke Hayashi, Soji Shimizu, Ji Young Shin, Nagao Kobayashi, Hiroshi Shinokubo

研究成果: ジャーナルへの寄稿記事

94 引用 (Scopus)

抄録

Small is beautiful: A ring-contracted sister of porphyrin, norcorrole, has been synthesized efficiently as a stable molecule by a nickel-templated strategy. The norcorrole complex is stable but exhibits a distinct antiaromatic character according to the Hückel rule. Oxidation of the norcorrole complex provides an aromatic oxacorrole complex.

元の言語英語
ページ(範囲)8542-8545
ページ数4
ジャーナルAngewandte Chemie - International Edition
51
発行部数34
DOI
出版物ステータス出版済み - 8 20 2012
外部発表Yes

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Porphyrins
Nickel
Oxidation
Molecules

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

これを引用

Gram-scale synthesis of nickel(II) norcorrole : The smallest antiaromatic porphyrinoid. / Ito, Tomohiro; Hayashi, Yosuke; Shimizu, Soji; Shin, Ji Young; Kobayashi, Nagao; Shinokubo, Hiroshi.

:: Angewandte Chemie - International Edition, 巻 51, 番号 34, 20.08.2012, p. 8542-8545.

研究成果: ジャーナルへの寄稿記事

Ito, Tomohiro ; Hayashi, Yosuke ; Shimizu, Soji ; Shin, Ji Young ; Kobayashi, Nagao ; Shinokubo, Hiroshi. / Gram-scale synthesis of nickel(II) norcorrole : The smallest antiaromatic porphyrinoid. :: Angewandte Chemie - International Edition. 2012 ; 巻 51, 番号 34. pp. 8542-8545.
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