Guest-Dependent Spin-Transition Behavior of Porous Coordination Polymers

Ryo Ohtani, Shinya Hayami

研究成果: Contribution to journalReview article査読

53 被引用数 (Scopus)

抄録

The host–guest composites of Hofmann-type iron(II) spin-transition (ST) porous coordination polymers incorporating guest molecules show guest-dependent ST behavior in accordance with the respective guest species, which may be a gas, solvent, halogen, or organic molecule. The guest also works as a chemical stimulant to switch the spin state of the host between high and low spin at room temperature. In this review, we discuss guest properties including size, shape, flexibility, chemical properties, and pore loading content, which impact the spin states of the host framework and the ST behavior exhibited by the host–guest composites.

本文言語英語
ページ(範囲)2236-2248
ページ数13
ジャーナルChemistry - A European Journal
23
10
DOI
出版ステータス出版済み - 2 16 2017
外部発表はい

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

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