Helical structures of conjugate polymers created by oxidative polymerization using synthetic lipid assemblies as templates

Tsukasa Hatano, Ah Hyun Bae, Masayuki Takeuchi, Norifumi Fujita, Kenji Kaneko, Hirotaka Ihara, Makoto Takafuji, Seiji Shinkai

研究成果: ジャーナルへの寄稿学術誌査読

25 被引用数 (Scopus)

抄録

The morphology of conjugate polymers (such as poly(ethylenedioxythiophene), poly (pyrrole), and poly(aniline)) can be controlled in their polymerization processes, by applying the concept of the templating method to oxidative polymerization. As oxidative polymerization of these monomers produces cationic intermediates, the anionic assemblies can act as potential templates due to the mutual electrostatic attractive force. Oxidative polymerization of ethylenedioxythiophene (EDOT), pyrrole, and aniline was carried out using helical superstructures of synthetic lipid assemblies as templates. Interestingly, we have found that oxidative polymerization of these monomers results in novel polymeric aggregates, such as a helical-tape structure and an intertwined helical structure, and that both the right-handed and left-handed helical structures can be created by a change in the hydrophilic head groups. This is the first example of helical superstructures composed of conjugate polymers that have been designed utilizing a convenient templating method.

本文言語英語
ページ(範囲)5067-5075
ページ数9
ジャーナルChemistry - A European Journal
10
20
DOI
出版ステータス出版済み - 10月 11 2004

!!!All Science Journal Classification (ASJC) codes

  • 触媒
  • 有機化学

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