抄録
Herein, we report the synthesis of a novel heterohexanuclear complex (1) of a heteroaromatic cofactor, pyrroloquinolinequinone (PQQ). The crystal structure of 1 was determined to reveal that two PQQ-bridged RuIIAg I units were linked by two [AgI(OTf)2] - units (OTf = CF3SO3-). A solvent-bound RuIIAgI heterodinuclear complex (2) was formed from 1 in a coordinating solvent such as acetone to show an intense metal-to-ligand charge-transfer band at 709 nm.
本文言語 | 英語 |
---|---|
ページ(範囲) | 2274-2276 |
ページ数 | 3 |
ジャーナル | Inorganic chemistry |
巻 | 52 |
号 | 5 |
DOI | |
出版ステータス | 出版済み - 3月 4 2013 |
!!!All Science Journal Classification (ASJC) codes
- 物理化学および理論化学
- 無機化学