抄録
Herein, we report the synthesis of a novel heterohexanuclear complex (1) of a heteroaromatic cofactor, pyrroloquinolinequinone (PQQ). The crystal structure of 1 was determined to reveal that two PQQ-bridged RuIIAg I units were linked by two [AgI(OTf)2] - units (OTf = CF3SO3 -). A solvent-bound RuIIAgI heterodinuclear complex (2) was formed from 1 in a coordinating solvent such as acetone to show an intense metal-to-ligand charge-transfer band at 709 nm.
| 元の言語 | 英語 |
|---|---|
| ページ（範囲） | 2274-2276 |
| ページ数 | 3 |
| ジャーナル | Inorganic Chemistry |
| 巻 | 52 |
| 発行部数 | 5 |
| DOI | |
| 出版物ステータス | 出版済み - 3 11 2013 |
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All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Inorganic Chemistry
これを引用
Heteronuclear RuIIAgI complexes having a pyrroloquinolinequinone derivative as a bridging ligand. / Mitome, Hiroumi; Ishizuka, Tomoya; Shiota, Yoshihito; Yoshizawa, Kazunari; Kojima, Takahiko.
：: Inorganic Chemistry, 巻 52, 番号 5, 11.03.2013, p. 2274-2276.研究成果: ジャーナルへの寄稿 › 記事
}
TY - JOUR
T1 - Heteronuclear RuIIAgI complexes having a pyrroloquinolinequinone derivative as a bridging ligand
AU - Mitome, Hiroumi
AU - Ishizuka, Tomoya
AU - Shiota, Yoshihito
AU - Yoshizawa, Kazunari
AU - Kojima, Takahiko
PY - 2013/3/11
Y1 - 2013/3/11
N2 - Herein, we report the synthesis of a novel heterohexanuclear complex (1) of a heteroaromatic cofactor, pyrroloquinolinequinone (PQQ). The crystal structure of 1 was determined to reveal that two PQQ-bridged RuIIAg I units were linked by two [AgI(OTf)2] - units (OTf = CF3SO3 -). A solvent-bound RuIIAgI heterodinuclear complex (2) was formed from 1 in a coordinating solvent such as acetone to show an intense metal-to-ligand charge-transfer band at 709 nm.
AB - Herein, we report the synthesis of a novel heterohexanuclear complex (1) of a heteroaromatic cofactor, pyrroloquinolinequinone (PQQ). The crystal structure of 1 was determined to reveal that two PQQ-bridged RuIIAg I units were linked by two [AgI(OTf)2] - units (OTf = CF3SO3 -). A solvent-bound RuIIAgI heterodinuclear complex (2) was formed from 1 in a coordinating solvent such as acetone to show an intense metal-to-ligand charge-transfer band at 709 nm.
UR - http://www.scopus.com/inward/record.url?scp=84874616750&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84874616750&partnerID=8YFLogxK
U2 - 10.1021/ic302617b
DO - 10.1021/ic302617b
M3 - Article
VL - 52
SP - 2274
EP - 2276
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 5
ER -