Heteronuclear RuIIAgI complexes having a pyrroloquinolinequinone derivative as a bridging ligand

Hiroumi Mitome; Tomoya Ishizuka; Yoshihiko Shiota; Kazunari Yoshizawa; Takahiko Kojima

doi:10.1021/ic302617b

Heteronuclear Ru^IIAg^I complexes having a pyrroloquinolinequinone derivative as a bridging ligand

Hiroumi Mitome, Tomoya Ishizuka, Yoshihiko Shiota, Kazunari Yoshizawa, Takahiko Kojima

物質基盤化学部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

7 被引用数 (Scopus)

抄録

Herein, we report the synthesis of a novel heterohexanuclear complex (1) of a heteroaromatic cofactor, pyrroloquinolinequinone (PQQ). The crystal structure of 1 was determined to reveal that two PQQ-bridged Ru^IIAg ^I units were linked by two [Ag^I(OTf)₂] ^- units (OTf = CF₃SO₃^-). A solvent-bound Ru^IIAg^I heterodinuclear complex (2) was formed from 1 in a coordinating solvent such as acetone to show an intense metal-to-ligand charge-transfer band at 709 nm.

本文言語	英語
ページ（範囲）	2274-2276
ページ数	3
ジャーナル	Inorganic chemistry
巻	52
号	5
DOI	https://doi.org/10.1021/ic302617b
出版ステータス	出版済み - 3月 4 2013

!!!All Science Journal Classification (ASJC) codes

物理化学および理論化学
無機化学

文献へのアクセス

10.1021/ic302617b

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引用スタイル

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author = "Hiroumi Mitome and Tomoya Ishizuka and Yoshihiko Shiota and Kazunari Yoshizawa and Takahiko Kojima",

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T1 - Heteronuclear RuIIAgI complexes having a pyrroloquinolinequinone derivative as a bridging ligand

AU - Mitome, Hiroumi

AU - Ishizuka, Tomoya

AU - Shiota, Yoshihiko

AU - Yoshizawa, Kazunari

AU - Kojima, Takahiko

PY - 2013/3/4

Y1 - 2013/3/4

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AB - Herein, we report the synthesis of a novel heterohexanuclear complex (1) of a heteroaromatic cofactor, pyrroloquinolinequinone (PQQ). The crystal structure of 1 was determined to reveal that two PQQ-bridged RuIIAg I units were linked by two [AgI(OTf)2] - units (OTf = CF3SO3-). A solvent-bound RuIIAgI heterodinuclear complex (2) was formed from 1 in a coordinating solvent such as acetone to show an intense metal-to-ligand charge-transfer band at 709 nm.

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