High-Crystallinity π-Conjugated Small Molecules Based on Thienylene-Vinylene-Thienylene

Critical Role of Self-Organization in Photovoltaic, Charge-Transport, and Morphological Properties

Seiichi Furukawa, Hideaki Komiyama, Naoya Aizawa, Takuma Yasuda

研究成果: ジャーナルへの寄稿記事

1 引用 (Scopus)

抄録

Narrow-band-gap small molecules with π-extended backbones are promising donor materials for solution-processed bulk-heterojunction (BHJ) organic solar cells (OSCs). Herein, a series of acceptor-donor-acceptor (A-D-A) photovoltaic small molecules incorporating thienylene-vinylene-thienylene (TVT) as a central D unit and alkyl-substituted rhodanine or 2-(1,1-dicyanomethylene)rhodanine as terminal A units are designed and synthesized. Their physical properties including photoabsorption, electronic energy levels, hole mobility, and morphological characteristics are systematically investigated. Using solvent vapor annealing (SVA), the morphologies of the BHJ photoactive layers composed of these small-molecule donors and a [6,6]-phenyl-C 71 -butyric acid methyl ester (PC 71 BM) acceptor can be properly modulated. As a result of increased crystallinity of the donors and desired phase segregation between the donors and PC 71 BM upon rapid SVA treatment, the photovoltaic performances of the resultant OSC devices undergo drastic enhancement. The results reported here indicate that high-efficiency small-molecule OSCs can be achieved through rational design of the TVT-based molecular framework and optimization of the nanoscale phase-segregated morphology via proper SVA treatment.

元の言語英語
ページ(範囲)42756-42765
ページ数10
ジャーナルACS Applied Materials and Interfaces
10
発行部数49
DOI
出版物ステータス出版済み - 12 12 2018

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Charge transfer
Rhodanine
Molecules
Butyric acid
Butyric Acid
Vapors
Annealing
Heterojunctions
Esters
Hole mobility
Electron energy levels
Energy gap
Physical properties
Organic solar cells

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

これを引用

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title = "High-Crystallinity {\"I}€-Conjugated Small Molecules Based on Thienylene-Vinylene-Thienylene: Critical Role of Self-Organization in Photovoltaic, Charge-Transport, and Morphological Properties",
abstract = "Narrow-band-gap small molecules with {\"I}€-extended backbones are promising donor materials for solution-processed bulk-heterojunction (BHJ) organic solar cells (OSCs). Herein, a series of acceptor-donor-acceptor (A-D-A) photovoltaic small molecules incorporating thienylene-vinylene-thienylene (TVT) as a central D unit and alkyl-substituted rhodanine or 2-(1,1-dicyanomethylene)rhodanine as terminal A units are designed and synthesized. Their physical properties including photoabsorption, electronic energy levels, hole mobility, and morphological characteristics are systematically investigated. Using solvent vapor annealing (SVA), the morphologies of the BHJ photoactive layers composed of these small-molecule donors and a [6,6]-phenyl-C 71 -butyric acid methyl ester (PC 71 BM) acceptor can be properly modulated. As a result of increased crystallinity of the donors and desired phase segregation between the donors and PC 71 BM upon rapid SVA treatment, the photovoltaic performances of the resultant OSC devices undergo drastic enhancement. The results reported here indicate that high-efficiency small-molecule OSCs can be achieved through rational design of the TVT-based molecular framework and optimization of the nanoscale phase-segregated morphology via proper SVA treatment.",
author = "Seiichi Furukawa and Hideaki Komiyama and Naoya Aizawa and Takuma Yasuda",
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AU - Komiyama, Hideaki

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AU - Yasuda, Takuma

PY - 2018/12/12

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