High-performance thermoelectric mineral Cu12-xNi xSb4S13 tetrahedrite

Koichiro Suekuni, Kojiro Tsuruta, Masaru Kunii, Hirotaka Nishiate, Eiji Nishibori, Sachiko Maki, Michihiro Ohta, Atsushi Yamamoto, Mikio Koyano

研究成果: ジャーナルへの寄稿学術誌査読

224 被引用数 (Scopus)

抄録

X-ray structural analysis and high-temperature thermoelectric properties measurements are performed on polycrystalline samples of artificial mineral Cu12-xNixSb4S13 tetrahedrite. Analysis of the atomic displacement parameter manifests low-energy vibration of Cu(2) out of CuS3 triangle plane. The vibration results in low lattice thermal conductivity of less than 0.5 W K-1 m -1. By tuning of the Ni composition x and decrease of electronic thermal conductivity, dimensionless thermoelectric figure of merit for x = 1.5 achieves 0.7 at 665 K, which is a considerably high value among p-type Pb-free sulfides. Because the tetrahedrite is an environmentally friendly material, it constitutes a good thermoelectric material for use in support of a sustainable society.

本文言語英語
論文番号043712
ジャーナルJournal of Applied Physics
113
4
DOI
出版ステータス出版済み - 1月 28 2013
外部発表はい

!!!All Science Journal Classification (ASJC) codes

  • 物理学および天文学(全般)

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