High-pressure TiO2-II polymorph as an active photocatalyst for CO2 to CO conversion

Saeid Akrami, Monotori Watanabe, Tan Hui Ling, Tatsumi Ishihara, Makoto Arita, Masayoshi Fuji, Kaveh Edalati

研究成果: Contribution to journalArticle査読

2 被引用数 (Scopus)

抄録

Rutile and anatase titanium oxide phases are widely used for photocatalytic CO2 conversion, and there have been significant attempts to improve their activity by various chemical methods. In this study, we show that the nanocrystalline high-pressure TiO2-II polymorph, synthesized by a high-pressure technique, shows higher photocurrent and better photocatalytic activity for CO2 to CO conversion compared to the anatase phase. The photocatalytic activity of material is further enhanced by thermal annihilation of oxygen vacancies generated in the bulk of TiO2-II during the high-pressure treatment. The high potential of TiO2-II phase for CO2 conversion is discussed based on the light absorbance, band structure, charge carrier mobility and CO2 adsorption.

本文言語英語
論文番号120566
ジャーナルApplied Catalysis B: Environmental
298
DOI
出版ステータス出版済み - 12 5 2021

All Science Journal Classification (ASJC) codes

  • 触媒
  • 環境科学(全般)
  • プロセス化学およびプロセス工学

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