High total proton conductivity in large-grained yttrium-doped barium zirconate

Yoshihiro Yamazaki, Raul Hernandez-Sanchez, Sossina M. Haile

研究成果: ジャーナルへの寄稿学術誌査読

367 被引用数 (Scopus)


Barium zirconate has attracted particular attention among candidate proton conducting electrolyte materials for fuel cells and other electrochemical applications because of its chemical stability, mechanical robustness, and high bulk proton conductivity. Development of electrochemical devices based on this material, however, has been hampered by the high resistance of grain boundaries, and, due to limited grain growth during sintering, the high number density of such boundaries. Here, we demonstrate a fabrication protocol based on the sol - gel synthesis of nanocrystalline precursor materials and reactive sintering that results in large-grained, polycrystalline BaZr 0.8Y 0.2C 3-δ of total high conductivity, ∼ 1 × 10 -2 Scm -1 at 450 °C. The detrimental role of grain boundaries in these materials is confirmed via a comparison of the conductivities of polycrystalline samples with different grain sizes. Specifically, two samples with grain sizes differing by a factor of 2.3 display essentially identical grain interior conductivities, whereas the total grain boundary conductivities differ by a factor of 2.5-3.2, depending on the temperature (with the larger-grained material displaying higher conductivity).

ジャーナルChemistry of Materials
出版ステータス出版済み - 7月 14 2009

!!!All Science Journal Classification (ASJC) codes

  • 化学 (全般)
  • 化学工学(全般)
  • 材料化学


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