抄録
Racemic 3-cyclohexyl-1-methyldiaziridine was found to react with α,β-unsaturated amides in basic conditions, giving N-unprotected trans-aziridines, while 3,3-pentamethylenediaziridine had been reported to afford cis-aziridines in high diastereoselectivity. The trans-selectivity was partially dependent on the stereochemistry of the substrate. The stereochemistries of these reactions were reasonably explained by the conformational analysis of the intermediary enolates.
| 本文言語 | 英語 |
|---|---|
| ページ（範囲） | 984-985 |
| ページ数 | 2 |
| ジャーナル | Chemistry Letters |
| 号 | 10 |
| DOI | |
| 出版ステータス | 出版済み - 2001 |
!!!All Science Journal Classification (ASJC) codes
- 化学 (全般)