抄録
Racemic 3-cyclohexyl-1-methyldiaziridine was found to react with α,β-unsaturated amides in basic conditions, giving N-unprotected trans-aziridines, while 3,3-pentamethylenediaziridine had been reported to afford cis-aziridines in high diastereoselectivity. The trans-selectivity was partially dependent on the stereochemistry of the substrate. The stereochemistries of these reactions were reasonably explained by the conformational analysis of the intermediary enolates.
本文言語 | 英語 |
---|---|
ページ(範囲) | 984-985 |
ページ数 | 2 |
ジャーナル | Chemistry Letters |
号 | 10 |
DOI | |
出版ステータス | 出版済み - 2001 |
!!!All Science Journal Classification (ASJC) codes
- 化学 (全般)