Highly efficient extraction separation of lanthanides using a diglycolamic acid extractant

Kojiro Shimojo, Noboru Aoyagi, Takumi Saito, Hiroyuki Okamura, Fukiko Kubota, Masahiro Goto, Hirochika Naganawa

研究成果: Contribution to journalArticle査読

34 被引用数 (Scopus)

抄録

Liquid-liquid extraction of lanthanide ions (Ln 3+ ) using N,N-dioctyldiglycolamic acid (DODGAA) was comprehensively investigated, together with fluorescence spectroscopic characterization of the resulting extracted complexes in the organic phase. DODGAA enables the quantitative partitioning of all Ln 3+ ions from moderately acidic solutions, while showing selectivity for heavier lanthanides, and provides remarkably high extraction separation performance for Ln 3+ compared with typical carboxylic acid extractants. Furthermore, the mutual separation abilities of DODGAA for light lanthanides are higher than those of organophosphorus extractants. Slope analysis, loading tests, and electrospray ionization mass spectrometry measurements demonstrated that the transfer of Ln 3+ with DODGAA proceeded through a proton-exchange reaction, forming a 1:3 complex, Ln(DODGAA) 3 . The stripping of Ln 3+ from the extracting phase was successfully achieved under acidic conditions. Time-resolved laser-induced fluorescence spectroscopy revealed that the extracted Eu 3+ ions were completely dehydrated by complexation with DODGAA.

本文言語英語
ページ(範囲)263-269
ページ数7
ジャーナルanalytical sciences
30
2
DOI
出版ステータス出版済み - 2 2014

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry

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