Highly efficient photocatalytic water reduction with robust iridium(III) photosensitizers containing arylsilyl substituents

Dong Ryeol Whang, Ken Sakai, Soo Young Park

研究成果: Contribution to journalArticle査読

58 被引用数 (Scopus)

抄録

Waterproof complexes: Cationic IrIII photosensitizers (PSs) with an ancillary 4,4′-bis(4-(triphenylsilyl)phenyl)-2,2′-bipyridine ligand enabled hydrogen evolution from water with high turnover numbers (TONs; see scheme). The peripheral triphenylsilyl moieties prevent ligand substitution by solvent molecules, such as water, and thus increase the durability of the complexes. SR=sacrificial reducing agent, WRC=water-reduction catalyst.

本文言語英語
ページ(範囲)11612-11615
ページ数4
ジャーナルAngewandte Chemie - International Edition
52
44
DOI
出版ステータス出版済み - 10 25 2013

All Science Journal Classification (ASJC) codes

  • 触媒
  • 化学 (全般)

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