Highly efficient synthesis of aldenamines from carboxamides by iridium-catalyzed silane-reduction/dehydration under mild conditions

Yukihiro Motoyama; Masaharu Aoki; Naoki Takaoka; Ryuta Aoto; Hideo Nagashima

doi:10.1039/b821317h

Highly efficient synthesis of aldenamines from carboxamides by iridium-catalyzed silane-reduction/dehydration under mild conditions

Yukihiro Motoyama, Masaharu Aoki, Naoki Takaoka, Ryuta Aoto, Hideo Nagashima

分子集積化学部門

研究成果: ジャーナルへの寄稿 › 学術誌 › 査読

125 被引用数 (Scopus)

抄録

The combination of IrCl(CO)(PPh₃)₂ with 1,1,3,3-tetramethyldisiloxane or poly(methylhydrosiloxane) (PMHS) is found to be an efficient catalyst system for the preparation of aldenamines from carboxamides; in particular, facile removal of silicone and iridium residues from the product can be achieved by the use of PMHS.

本文言語	英語
ページ（範囲）	1574-1576
ページ数	3
ジャーナル	Chemical Communications
号	12
DOI	https://doi.org/10.1039/b821317h
出版ステータス	出版済み - 2009

!!!All Science Journal Classification (ASJC) codes

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

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10.1039/b821317h

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引用スタイル

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abstract = "The combination of IrCl(CO)(PPh3)2 with 1,1,3,3-tetramethyldisiloxane or poly(methylhydrosiloxane) (PMHS) is found to be an efficient catalyst system for the preparation of aldenamines from carboxamides; in particular, facile removal of silicone and iridium residues from the product can be achieved by the use of PMHS.",

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AU - Aoto, Ryuta

AU - Nagashima, Hideo

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