Highly enantioselective Baeyer-Villiger oxidation using Zr(salen) complex as catalyst

Akira Watanabe; Tatsuya Uchida; Katsuji Ito; Tsutomu Katsuki

doi:10.1016/S0040-4039(02)00831-6

Highly enantioselective Baeyer-Villiger oxidation using Zr(salen) complex as catalyst

Akira Watanabe, Tatsuya Uchida, Katsuji Ito, Tsutomu Katsuki

自然科学実験系部門

研究成果: Contribution to journal › Article › 査読

102 被引用数 (Scopus)

抄録

(R, R)-Zr(salen) complex was found to serve as an efficient catalyst for asymmetric Baeyer-Villiger oxidation of pro-chiral and racemic ketones using urea·hydrogen peroxide as the terminal oxidant: for example, high enantioselectivity of 87% ee was achieved in the Baeyer-Villiger reaction of 3-phenylcyclobutanone.

本文言語	英語
ページ（範囲）	4481-4485
ページ数	5
ジャーナル	Tetrahedron Letters
巻	43
号	25
DOI	https://doi.org/10.1016/S0040-4039(02)00831-6
出版ステータス	出版済み - 1 1 2002

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

文献へのアクセス

10.1016/S0040-4039(02)00831-6

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引用スタイル

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