Highly stereoselective approach to chiral building block possessing three contiguous asymmetric centers. Preparation of four possible diastereomers of β,β′-dimethyl-bis-homoallylic alcohol derivative

Keisuke Suzuki, Eiji Katayama, Katsuhiko Tomooka, Takashi Matsumoto, Gen ichi Tsuchihashi

研究成果: ジャーナルへの寄稿記事

13 引用 (Scopus)

抄録

All four diastereomere of chiral alcohol 2 with three contiguous chiral centers were stereoselectively prepared via diastereoselective addition of nucleophiles (crotyl metal or H-) to α-methyl-β,γ-unsaturated carbonyl compounds 1.

元の言語英語
ページ(範囲)3707-3710
ページ数4
ジャーナルTetrahedron Letters
26
発行部数31
DOI
出版物ステータス出版済み - 1 1 1985
外部発表Yes

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Carbonyl compounds
Nucleophiles
Metals
Alcohols
Derivatives

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

これを引用

Highly stereoselective approach to chiral building block possessing three contiguous asymmetric centers. Preparation of four possible diastereomers of β,β′-dimethyl-bis-homoallylic alcohol derivative. / Suzuki, Keisuke; Katayama, Eiji; Tomooka, Katsuhiko; Matsumoto, Takashi; Tsuchihashi, Gen ichi.

:: Tetrahedron Letters, 巻 26, 番号 31, 01.01.1985, p. 3707-3710.

研究成果: ジャーナルへの寄稿記事

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abstract = "All four diastereomere of chiral alcohol 2 with three contiguous chiral centers were stereoselectively prepared via diastereoselective addition of nucleophiles (crotyl metal or H-) to α-methyl-β,γ-unsaturated carbonyl compounds 1.",
author = "Keisuke Suzuki and Eiji Katayama and Katsuhiko Tomooka and Takashi Matsumoto and Tsuchihashi, {Gen ichi}",
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AU - Tomooka, Katsuhiko

AU - Matsumoto, Takashi

AU - Tsuchihashi, Gen ichi

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