Homogeneous catalysis of platinum(II) complexes in photochemical hydrogen production from water

研究成果: Contribution to journalReview article査読

201 被引用数 (Scopus)

抄録

This review concentrates on the Pt(II)-catalyzed reduction of water into molecular hydrogen, with emphasis given to the works undertaken thus far by the authors' group. The homogeneous catalysis of (i) dinuclear platinum(II) complexes, (ii) mononuclear platinum(II) complexes, (iii) platinum(II) complexes having electron-acceptor groups, and (iv) platinum(II) complexes having photosensitizing groups is described. The dependences of the H2-evolving activity on the metal-metal interaction, the Pt(II) dz2 orbital energy, the steric factor, and the electron-acceptor ability are discussed. Moreover, the first active model of a photo-hydrogen-evolving molecular device made up of a tris(2,2′-bipyridine)ruthenium(II) derivative and a homogeneous platinum(II) catalyst is discussed.

本文言語英語
ページ(範囲)2753-2766
ページ数14
ジャーナルCoordination Chemistry Reviews
251
21-24
DOI
出版ステータス出版済み - 11 2007

All Science Journal Classification (ASJC) codes

  • 物理化学および理論化学
  • 無機化学
  • 材料化学

フィンガープリント

「Homogeneous catalysis of platinum(II) complexes in photochemical hydrogen production from water」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル