Homogeneous Pd-catalyzed transformation of terminal alkenes into primary allylic alcohols and derivatives

Ren Tomita, Kohei Mantani, Akiyuki Hamasaki, Tamao Ishida, Makoto Tokunaga

研究成果: ジャーナルへの寄稿記事

11 引用 (Scopus)

抄録

Synthesis of primary alcohols from terminal alkenes is an important process in both bulk and fine chemical syntheses. Herein, a homogeneous Pd-complex-catalyzed transformation of terminal alkenes into primary allylic alcohols, by using 5 mol % [Pd(PPh3)4] as a catalyst, and H2O, CO2, and quinone derivatives as reagents, is reported. When alcohols were used instead of H2O, allylic ethers were obtained. A proposed mechanism includes the addition of oxygen nucleophiles at the less-hindered terminal position of π-allyl Pd intermediates.

元の言語英語
ページ(範囲)9914-9917
ページ数4
ジャーナルChemistry - A European Journal
20
発行部数32
DOI
出版物ステータス出版済み - 8 4 2014

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Alkenes
Olefins
Alcohols
Derivatives
Nucleophiles
Ethers
Oxygen
Catalysts
allyl alcohol
benzoquinone

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Organic Chemistry

これを引用

Homogeneous Pd-catalyzed transformation of terminal alkenes into primary allylic alcohols and derivatives. / Tomita, Ren; Mantani, Kohei; Hamasaki, Akiyuki; Ishida, Tamao; Tokunaga, Makoto.

:: Chemistry - A European Journal, 巻 20, 番号 32, 04.08.2014, p. 9914-9917.

研究成果: ジャーナルへの寄稿記事

Tomita, Ren ; Mantani, Kohei ; Hamasaki, Akiyuki ; Ishida, Tamao ; Tokunaga, Makoto. / Homogeneous Pd-catalyzed transformation of terminal alkenes into primary allylic alcohols and derivatives. :: Chemistry - A European Journal. 2014 ; 巻 20, 番号 32. pp. 9914-9917.
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AU - Tokunaga, Makoto

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