Horizontal molecular orientation of light-emitting oligofluorenes in spin-coated glassy organic thin films

Li Zhao, Takeshi Komino, Dae Hyeon Kim, Muhammad Hasnan Sazzad, Delphine Pitrat, Jean Christophe Mulatier, Chantal Andraud, Jean Charles Ribierre, Chihaya Adachi

研究成果: Contribution to journalArticle査読

14 被引用数 (Scopus)

抄録

Horizontal orientation of light-emitting chromophores plays a critical role in the light outcoupling efficiency and the overall performances of organic light-emitting diodes. Here, we demonstrate that such a horizontal orientation of light-emitting molecules can be achieved in solution-processed blends containing highly fluorescent oligofluorenes dispersed into various small molecule host materials. The influences of the host material, the solvent used for the spin-coating, the doping concentration of the oligofluorenes and the oligofluorene chemical structure on these orientational processes are investigated using variable angle spectroscopic ellipsometry and angle-dependent photoluminescence measurements. By clarifying the roles played by these parameters in the horizontal orientation of the emitters, the results provide crucial insights into these molecular orientational processes in spin-coated glassy organic thin films, which should be relevant for the development of high-efficiency solution-processed organic light-emitting diodes in the near future.

本文言語英語
ページ(範囲)11557-11565
ページ数9
ジャーナルJournal of Materials Chemistry C
4
48
DOI
出版ステータス出版済み - 2016

All Science Journal Classification (ASJC) codes

  • 化学 (全般)
  • 材料化学

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