HRTEM / EELS analysis, structural characterization and sensor performances of hydrothermal nano-TiO2

Ana M. Ruiz, J. Arbiol, A. Cornet, K. Shimanoe, Joan R. Morante, N. Yamazoe

研究成果: ジャーナルへの寄稿Conference article

9 引用 (Scopus)

抄録

Pure nanophased TiO2 with controlled microstructure and resistant to thermal induced grain growth has been prepared by hydrothermal treatments. The synthesized nano-TiO2 presents small size and well defined and faceted surface, as shown by Raman spectroscopy, XRD, EELS and HRTEM. Such performances are slightly changed with the posterior temperature treatments up to 700°C, maintaining anatase phase structure and grain size about 20nm. The extent of stabilization depended on the pH of the treatment, being pH 2 more convenient for stabilizing the size, and pH 3 for the phase. HRTEM and EELS measurements showed the coexistence of rutile big particles (∼100 nm) with anatase small particles (∼40 nm) at pH 3 and calcination at 900°C. Thick-films of precipitated TiO2 and hydrothermally treated TiO2 were tested for the CO and the ethanol response. The hydrothermal treatment allowed obtaining stable sensitive films which exhibited enlarged sensor response and improved transients, specially in the case of the materials treated at pH 3.

元の言語英語
記事番号A4.10
ページ(範囲)203-208
ページ数6
ジャーナルMaterials Research Society Symposium Proceedings
828
出版物ステータス出版済み - 6 20 2005
イベントSemiconductor Materials for Sensing - Boston, MA, 米国
継続期間: 11 29 200412 2 2004

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Electron energy loss spectroscopy
structural analysis
Structural analysis
Titanium dioxide
sensors
Sensors
Phase structure
Grain growth
Thick films
Calcination
Raman spectroscopy
Ethanol
Stabilization
anatase
Microstructure
Carbon Monoxide
rutile
roasting
thick films
ethyl alcohol

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

これを引用

HRTEM / EELS analysis, structural characterization and sensor performances of hydrothermal nano-TiO2. / Ruiz, Ana M.; Arbiol, J.; Cornet, A.; Shimanoe, K.; Morante, Joan R.; Yamazoe, N.

:: Materials Research Society Symposium Proceedings, 巻 828, A4.10, 20.06.2005, p. 203-208.

研究成果: ジャーナルへの寄稿Conference article

Ruiz, Ana M. ; Arbiol, J. ; Cornet, A. ; Shimanoe, K. ; Morante, Joan R. ; Yamazoe, N. / HRTEM / EELS analysis, structural characterization and sensor performances of hydrothermal nano-TiO2. :: Materials Research Society Symposium Proceedings. 2005 ; 巻 828. pp. 203-208.
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abstract = "Pure nanophased TiO2 with controlled microstructure and resistant to thermal induced grain growth has been prepared by hydrothermal treatments. The synthesized nano-TiO2 presents small size and well defined and faceted surface, as shown by Raman spectroscopy, XRD, EELS and HRTEM. Such performances are slightly changed with the posterior temperature treatments up to 700°C, maintaining anatase phase structure and grain size about 20nm. The extent of stabilization depended on the pH of the treatment, being pH 2 more convenient for stabilizing the size, and pH 3 for the phase. HRTEM and EELS measurements showed the coexistence of rutile big particles (∼100 nm) with anatase small particles (∼40 nm) at pH 3 and calcination at 900°C. Thick-films of precipitated TiO2 and hydrothermally treated TiO2 were tested for the CO and the ethanol response. The hydrothermal treatment allowed obtaining stable sensitive films which exhibited enlarged sensor response and improved transients, specially in the case of the materials treated at pH 3.",
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AU - Ruiz, Ana M.

AU - Arbiol, J.

AU - Cornet, A.

AU - Shimanoe, K.

AU - Morante, Joan R.

AU - Yamazoe, N.

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N2 - Pure nanophased TiO2 with controlled microstructure and resistant to thermal induced grain growth has been prepared by hydrothermal treatments. The synthesized nano-TiO2 presents small size and well defined and faceted surface, as shown by Raman spectroscopy, XRD, EELS and HRTEM. Such performances are slightly changed with the posterior temperature treatments up to 700°C, maintaining anatase phase structure and grain size about 20nm. The extent of stabilization depended on the pH of the treatment, being pH 2 more convenient for stabilizing the size, and pH 3 for the phase. HRTEM and EELS measurements showed the coexistence of rutile big particles (∼100 nm) with anatase small particles (∼40 nm) at pH 3 and calcination at 900°C. Thick-films of precipitated TiO2 and hydrothermally treated TiO2 were tested for the CO and the ethanol response. The hydrothermal treatment allowed obtaining stable sensitive films which exhibited enlarged sensor response and improved transients, specially in the case of the materials treated at pH 3.

AB - Pure nanophased TiO2 with controlled microstructure and resistant to thermal induced grain growth has been prepared by hydrothermal treatments. The synthesized nano-TiO2 presents small size and well defined and faceted surface, as shown by Raman spectroscopy, XRD, EELS and HRTEM. Such performances are slightly changed with the posterior temperature treatments up to 700°C, maintaining anatase phase structure and grain size about 20nm. The extent of stabilization depended on the pH of the treatment, being pH 2 more convenient for stabilizing the size, and pH 3 for the phase. HRTEM and EELS measurements showed the coexistence of rutile big particles (∼100 nm) with anatase small particles (∼40 nm) at pH 3 and calcination at 900°C. Thick-films of precipitated TiO2 and hydrothermally treated TiO2 were tested for the CO and the ethanol response. The hydrothermal treatment allowed obtaining stable sensitive films which exhibited enlarged sensor response and improved transients, specially in the case of the materials treated at pH 3.

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