Hydroalumination and related reactions of phenyl 1-(trimethylsilyl)propadienyl sulfide followed by quenching with carbonyl compounds

J. Tanaka, S. Kanemasa, O. Tsuge

研究成果: Contribution to journalArticle査読

2 被引用数 (Scopus)

抄録

Phenyl 1-(trimethylsilyl)propadienyl sulfide undergoes a hydroalumination with diisobutylaluminum hydride (DIBAH) or lithium butyl(diisobutyl)aluminum hydride (BL-DIBAH). The adduct anion derived from DIBAH is regioselectively trapped with carbonyl compounds at the position α to the phenylthio moiety to give 1,3-dienes as Peterson olefination products; the anion derived from BL-DIBAH is trapped at the position γ to the phenylthio moiety to give 3-buten-1-ols. Silylmetalation and stanylalumination on the same acceptor have been also briefly investigated as equivalent reactions.

本文言語英語
ページ(範囲)51-56
ページ数6
ジャーナルBulletin of the Chemical Society of Japan
63
1
DOI
出版ステータス出版済み - 1990

All Science Journal Classification (ASJC) codes

  • 化学 (全般)

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