Hydrogen Bond-Accelerated meta-Selective C-H Borylation of Aromatic Compounds and Expression of Functional Group and Substrate Specificities

Xu Lu, Yusuke Yoshigoe, Haruka Ida, Mitsumi Nishi, Motomu Kanai, Yoichiro Kuninobu

研究成果: ジャーナルへの寄稿学術誌査読

40 被引用数 (Scopus)

抄録

We found that meta-selective C-H borylation of aromatic compounds was accelerated when using urea moiety-containing bipyridine-type ligands unlike in cases involving a bipyridine-type ligand without the urea moiety. The acceleration was due to the recognition and capture of the aromatic substrates by the urea moiety of the ligand by hydrogen bonding. The acceleration was further enhanced by modifying the electronic and steric properties of the ligand. The functional group and substrate specificities were also observed using the urea moiety-containing ligands.

本文言語英語
ページ(範囲)1705-1709
ページ数5
ジャーナルACS Catalysis
9
3
DOI
出版ステータス出版済み - 3月 1 2019

!!!All Science Journal Classification (ASJC) codes

  • 触媒
  • 化学 (全般)

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