Hydrogen sorption in TiZrNbHfTa high entropy alloy

C. Zlotea, M. A. Sow, G. Ek, J. P. Couzinié, L. Perrière, I. Guillot, J. Bourgon, K. T. Møller, T. R. Jensen, E. Akiba, M. Sahlberg

研究成果: Contribution to journalArticle査読

53 被引用数 (Scopus)

抄録

High Entropy Alloys (HEA), where five or more elements are mixed together in near equiatomic ratios offer promising properties as hydrogen storage materials due to their ability to crystallize in simple cubic structures in the presence of large lattice strain originating from the different sizes of the atoms. In this work, the hydrogen absorption and desorption as well as the cycling properties of the TiZrNbHfTa HEA have been studied by in situ Synchrotron X-Ray diffraction, Pressure-Composition-Isotherm, Thermal Desorption Spectroscopy and Differential Scanning Calorimetry. The alloy crystallizes in a cubic bcc phase and undergoes a two-stage hydrogen absorption reaction to a fcc dihydride phase with an intermediate tetragonal monohydride, very similar to the V-H system. The hydrogen absorption/desorption in TiZrNbHfTa is completely reversible and the activation energy of desorption could be calculated. Furthermore, we have observed an interesting macrostructure following parallel planes after the formation of the dihydride phase, which is retained after desorption.

本文言語英語
ページ(範囲)667-674
ページ数8
ジャーナルJournal of Alloys and Compounds
775
DOI
出版ステータス出版済み - 2 15 2019

All Science Journal Classification (ASJC) codes

  • 材料力学
  • 機械工学
  • 金属および合金
  • 材料化学

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