抄録
Reduction of nitriles to silylated primary amines was achieved by combination of 1,1,3,3-tetramethyldisiloxane (TMDS) as the hydrosilane and a catalytic amount of Co(OPIV) 2 (PIV = CO t Bu) associated with isocyanide ligands. The resulting silylated amines were subjected to acid hydrolysis or treatment with acid chlorides to give the corresponding primary amines or imides in good yields. One-pot synthesis of primary amides to primary amines with hydrosilanes was also achieved by iron-cobalt dual catalyst systems.
本文言語 | 英語 |
---|---|
ページ(範囲) | 287-291 |
ページ数 | 5 |
ジャーナル | Organic letters |
巻 | 21 |
号 | 1 |
DOI | |
出版ステータス | 出版済み - 1月 4 2019 |
!!!All Science Journal Classification (ASJC) codes
- 生化学
- 物理化学および理論化学
- 有機化学