Hydrosilanes are not always reducing agents for carbonyl compounds but can also induce dehydration: A ruthenium-catalyzed conversion of primary amides to nitriles

Shiori Hanada, Yukihiro Motoyama, Hideo Nagashima

研究成果: Contribution to journalArticle査読

70 被引用数 (Scopus)

抄録

A practical procedure for production of nitriles is offered by the triruthenium carbonyl cluster catalyzed dehydration of primary carboxamides with hydrosilanes under neutral conditions. This is the first example that a transition-metal-catalyzed activation of Si-H bonds does not lead to the reduction of carbonyl compounds but to dehydration. Possible mechanisms for the dehydration is discussed on the basis of NMR spectroscopic detection of intermediary species.

本文言語英語
ページ(範囲)4097-4100
ページ数4
ジャーナルEuropean Journal of Organic Chemistry
24
DOI
出版ステータス出版済み - 8 2008

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry

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